Italy will face Ivory Coast at West Ham United's Upton Park on August 10.
The two sides have met just once before in Geneva five years ago in a match that ended 1-1.
Italy will be looking to return to winning ways after their humiliating exit from the World Cup in South Africa.
It also represents the dawn of a new era for the Azzurri with former Fiorentina boss Cesare Prandelli now at the helm.
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